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Dunn Edwards have provided an adsklib file for download that matches their paint colours to Revit materials.

I previously posted about Lysaght adsklib way back in 2011:
What Revit Wants: Lysaght Bluescope Colorbond Autodesk Material Library

I look forward to the day when all manufacturer materials come in adsklib format - would save us all some work :-)

Here are the Dunn Edwards links:

Revit Materials 
'adsklib' file (20mb)
  D.E. 5000 - 5093 colors

(dropbox access request)
http://www.arch-intel.info/revit-dunn-edwards-paint.html

They also provide some informative videos --

Getting the adsklib into Revit:
Setting up corresponding colours:

You want to be able to network and directly reference material libraries and resources.  You can do this using symbolic links in Windows 7 / 8, where the OS and applications think they are dealing with a local resource, when in fact it can be on the network.

Disclaimer:  I'm sure that there will still be some quirks and issues with this method - I doubt that it is the perfect solution.

This is the essential command:
To create a symbolic link type into the Command Prompt box
mklink /D
: This need to be exactly as per the location of the local machine path
e.g. “c:\Program Files\Common Files\Autodesk Shared\Materials\Textures\bluescope Lysaght”
*Don’t forget to use the double quotes, if it is not identical the library wont work.
: This is the location of your network files
e.g. “s:\bluescope Lysaght
*blueScope lysaght is the folder name

Check out this PDF for a more detailed description:
http://www.steelselect.com/download_centre/file.php?id=5039
(accessible via SteelSelect page here)

This method is also discussed at:
http://www.revitforum.org/third-party-add-ins-api-r-d/2883-colorbond%AE-steel-texture-library-revit-lysaght-content-beta-version-6.html#post87933
(but guess what, XP can't handle these symbolic links)